One‐Pot Synthesis of Carbon‐Supported Pd Nanoparticles with Ni and Carbon Matrix Protection for Durable Alkaline Hydrogen Oxidation Reaction - Université Grenoble Alpes
Article Dans Une Revue ChemCatChem Année : 2024

One‐Pot Synthesis of Carbon‐Supported Pd Nanoparticles with Ni and Carbon Matrix Protection for Durable Alkaline Hydrogen Oxidation Reaction

Résumé

Abstract Protecting nanoparticles with a carbon matrix can enhance the durability of the catalysts in alkaline fuel cells (AFC) and is well‐documented. While others have tried complex syntheses to produce small nanoparticle catalysts, in this work, in order to scale‐up batches of 15 g or more, carbon‐cap (or carbon‐coating) protected Vulcan XC72‐supported Pd−Ni (1–2) nanoparticles (Pd−Ni acc /C) were successfully synthesized via a one‐step dry‐synthesis process. This catalyst was compared with a commercial Pd−Ni/Vulcan XC72 material (PdNi/C, Premetek) in terms of hydrogen oxidation reaction (HOR) activity and stability. To produce less ordered carbon caps (versus graphite/graphene), a low‐temperature heat‐treatment (below 500 °C) was used, resulting in Pd−Ni acc /C of unique electrochemical properties: easily electrochemically activated, this catalyst outperforms PdNi/C for alkaline HOR and proves more durable under highly oxidizing accelerated stress test (AST) conditions. Identical location transmission electron microscopy (ILTEM), X‐ray photoelectron spectroscopy (XPS) and rotating disk electrode (RDE) measurements demonstrate how the Ni‐rich surface plays an important role in HOR activity for both PdNi/C and Pd‐Niacc/C and that the protective carbon‐coating of the latter ensures better durability of performance and better resistance to materials degradation.

Dates et versions

hal-04646839 , version 1 (12-07-2024)

Identifiants

Citer

Huong Doan, Ricardo Sgarbi, Quentin Labarde, Vincent Martin, Marian Chatenet. One‐Pot Synthesis of Carbon‐Supported Pd Nanoparticles with Ni and Carbon Matrix Protection for Durable Alkaline Hydrogen Oxidation Reaction. ChemCatChem, 2024, 487, pp.144159. ⟨10.1002/cctc.202400154⟩. ⟨hal-04646839⟩
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