Synthesis of symmetric and dissymmetric star-shaped pentaarylcyclopentadienyl Ru(II) complexes containing styryl-BODIPY fragments - Groupe Nanosciences
Journal Articles Chemistry Letters Year : 2024

Synthesis of symmetric and dissymmetric star-shaped pentaarylcyclopentadienyl Ru(II) complexes containing styryl-BODIPY fragments

Abstract

Abstract We synthesised star-shaped ruthenium(II) complexes containing one or five styryl-BODIPY units arranged around a central trisindazolylrutheniumcyclopentadienyl fragment. A symmetric complex was obtained following a five-fold Suzuki-Miyaura reaction of the pentabrominated key precursor while desymmetrisation was next achieved via a modular synthetic approach based on sequential chemoselective Suzuki-Miyaura reactions on a key building block bearing one iodophenyl and four bromophenyl groups.
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Dates and versions

hal-04637341 , version 1 (05-07-2024)

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Melissa Dumartin, Seifallah Abid, Yohan Gisbert, Nathalie Saffon-Merceron, Sheng Gao, et al.. Synthesis of symmetric and dissymmetric star-shaped pentaarylcyclopentadienyl Ru(II) complexes containing styryl-BODIPY fragments. Chemistry Letters, 2024, 53 (1), ⟨10.1093/chemle/upad003⟩. ⟨hal-04637341⟩
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