Synthesis of symmetric and dissymmetric star-shaped pentaarylcyclopentadienyl Ru(II) complexes containing styryl-BODIPY fragments
Abstract
Abstract We synthesised star-shaped ruthenium(II) complexes containing one or five styryl-BODIPY units arranged around a central trisindazolylrutheniumcyclopentadienyl fragment. A symmetric complex was obtained following a five-fold Suzuki-Miyaura reaction of the pentabrominated key precursor while desymmetrisation was next achieved via a modular synthetic approach based on sequential chemoselective Suzuki-Miyaura reactions on a key building block bearing one iodophenyl and four bromophenyl groups.
Domains
Chemical Sciences
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Chem Lett 2024.pdf (3.08 Mo)
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Chem Lett 2024 (1).pdf (3.08 Mo)
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Chem Lett 2024 (2).pdf (3.08 Mo)
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