How [Fe]-hydrogenase metabolizes dihydrogen

Abstract : Hydrogenases are very powerful biocatalysts for dihydrogen cleavage. Now, X-ray crystallography shows how [Fe]-hydrogenase requires ligand exchanges at the metal centre and significant molecular motions to open and close its active site to effectively transfer a hydride to an electrophilic organic substrate.
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Submitted on : Thursday, June 27, 2019 - 8:21:34 AM
Last modification on : Saturday, June 29, 2019 - 1:38:24 AM

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Yvain Nicolet. How [Fe]-hydrogenase metabolizes dihydrogen. Nature Catalysis, Nature Publishing Group, 2019, 2 (6), pp.481-482. ⟨10.1038/s41929-019-0296-5⟩. ⟨hal-02166639⟩

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